一價(jià)銅作為催化劑，端基炔和炔基鹵化物反應(yīng)生成非對稱性二炔的反應(yīng)
反應(yīng)機(jī)理：
最新文獻(xiàn)：
Copper(I) Iodide Catalyzed Cross-Coupling Reaction of Terminal Alkynes with 1-Bromoalkynes: A Simple Synthesis of Unsymmetrical Buta-1,3-diynes
S. Wang, L. Yu, P. Li, L. Meng, L. Wang, Synthesis, 2011, 1541-1546.
Bulky Trialkylsilyl Acetylenes in the Cadiot-Chodkiewicz Cross-Coupling Reaction
J. P. Marino, H. N. Nguyen, J. Org. Chem., 2002, 67, 6841-6844.
End-Cap Stabilized Oligoynes: Model Compounds for the Linear sp Carbon Allotrope Carbyne
T. Gibtner, F. Hampel, J.-P.Gisselbrecht, A. Hirsch, Chem. Eur. J., 2002, 68, 408-432.
編譯自：化學(xué)門戶
